Inorganic Synthesis and Catalysis Laboratory
Research group of Dr. Amrendra K. Singh
Our paper entitled “Ru(II) Complexes with Protic- and Anionic-Naked-NHC Ligands for Cooperative Activation of Small Molecules” has been published in Chemistry—A European Journal (DOI: https://doi.org/10.1002/chem.202301971). In this paper, a set of ruthenium(II)-protic-N-heterocyclic carbene complexes, [Ru(NNCH)(PPh3)2(X)]Cl (1, X=Cl and 2, X=H) and their deprotonated analogues [Ru(NNC)(PPh3)2(X)] (1ʹ, X=Cl and 2ʹ,X=H) are Read More …
Our paper entitled “Base-free synthesis of benchtop stable Ru(III)-NHC complexes from RuCl3·3H2O and their use as precursors for Ru(II)-NHC complexes” has been published in Dalton Transactions (DOI: https://doi.org/10.1039/D3DT00243H). In this paper, a series of Ru(III)-PyNHC complexes (1a-c), have been reported, prepared from simple starting materials via a base-free route, where Read More …
Congratulations to Dibya, Rahul and all the co-authors for the paper!! Our paper entitled “Cationic ruthenium(II)-NHC pincer complexes with hemilabile COD: Solid-state structural characterization and theoretical study of an η2-(E,Z)-COD ligand” has been published in the Journal of Organometallic Chemistry.
Congratulations to Dibya for her first paper from her PhD thesis work! Congratulations to all the co-authors of the paper!! Our paper entitled “Cationic ruthenium(II)–NHC pincer complexes: Synthesis, characterisation and catalytic activity for transfer hydrogenation of ketones” has been published in Applied Organometallic Chemistry.